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71.
72.
Reinhold Hartung Hans-Heinrich Möbius 《Fresenius' Journal of Analytical Chemistry》1994,349(8-9):571-574
Possibilities of the water-gas potentiometry using oxide ion-conducting solid electrolytes may be restricted by side reactions in the gas being analyzed. Changes in electrode potentials caused by simultaneous interfering equilibria in the water gas were investigated over a temperature range 1200 to 400°C for different initial gas compositions. Formation reactions of carbon and methane proved to be the side reactions which can be responsible for potential changes. Limits for the use of the analytical method are shown by graphs with deviations from the ideal values.77th report on oxide ion-conducting solid electrolytes and their possibilities of application; 76. see cfi/Ber. DKG (in press) 相似文献
73.
W. Hanke O. Schmitt H. Endres R. Kleiner P. Müller 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,5(3):465-471
A quantitative analysis of a microscopic model for the intrinsic Josephson effect in high-temperature superconductors based
on interlayer tunneling is presented both within a mean-field BCS evaluation and a numerically essentially exact Quantum Monte-Carlo
study. The pairing correlations in the CuO2-planes are modelled by a 2D Hubbard model with attractive interaction, a model which accounts well for some of the observed
features such as the short planar coherence length. The stack of Hubbard planes is arranged on a torus, which is threaded
by a magnetic flux. The current perpendicular to the planes is calculated as a function of applied flux (i.e. the phase), and - after careful elimination of finite-size effects due to single-particle tunneling - found to display a
sinusoidal field dependence in accordance with interlayer Josephson tunneling. Studies of the temperature dependence of the
supercurrent reveal at best a mild elevation of the Josephson transition temperature compared to the planar Kosterlitz-Thouless
temperature. These and other results on the dependence of the model parameters are compared with a standard BCS evaluation.
Received: 24 February 1998 / Revised: 28 April 1998 / Accepted: 23 June 1998 相似文献
74.
In a recent paper [O. Bärwald, R.W. Gebert, M. Günaydin and H. Nicolai, preprint KCL-MTH-97-22, IASSNS-HEP-97/20, PSU-TH-178, AEI-029, hep-th/9703084, to appear in Commun. Math. Phys.] it was conjectured that the imaginary simple roots of the Borcherds algebra II9,1 at level 1 are its only ones. We here propose an independent test of this conjecture, establishing its validity for all roots of norm − 8. However, the conjecture fails for roots of norm −10 and beyond, as we show by computing the simple multiplicities down to norm −24, which turn out to be remarkably small in comparison with the corresponding E10 multiplicities. Our derivation is based on a modified denominator formula combining the denominator formulas for E10 and II9,1, and provides an efficient method for determining the imaginary simple roots. In addition, we compute the E10 multiplicities of all roots up to height 231, including levels up to l = 6 and norms −42. 相似文献
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Bernhard Post Reinhold Hempfling Horst Klamberg und Hans-Rolf Schulten 《Fresenius' Journal of Analytical Chemistry》1988,331(3-4):273-281
Summary Humic acids prepared from four horizons of a Podzol in the Segeberger Forest as well as different fractions of humic substances (fulvi acid, humic acid, and humin) of the Ahe horizon were characterized by a combination of analytical methods. As basis served the data from elemental analyses, UV/VIS-, FTIR-, and 13C-NMR spectroscopy, gel permeation chromatography using Fractogel TSK, and vapor pressure osmometry. Utilizing pyrolysis in direct coupling with field ionization mass spectrometry, more detailed information about structural features of the humic substances in soils could be obtained. In this manner, the different importance of carbohydrates, aromatic, and lipidic components in the various fractions is observed. The characteristic temperature dependence of the averaged molecular weights of the pyrolyzates indicates a basic structural skeleton, which is quite similar for the humic acids isolated from the different horizons. By degradation of the carbohydrates and increasing incorporation of lipidic components an enhanced biotransformation takes place with increasing depth of the soil profile.
Gewidmet Herrn Professor Dr. W. Fresenius zum 75. Geburtstag 相似文献
Gewidmet Herrn Professor Dr. W. Fresenius zum 75. Geburtstag 相似文献
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